The Pokopia Starmie Doll was added with the Bubbly Basin DLC, giving players a way to access a new Dream Island based on the new underwater town. You should have no trouble finding the doll if you follow the story, but if you want it sooner - and know where to look - you can find the doll fairly quickly.
Either way, you're going to need a Dowsing Machine, so make sure you've got one in your inventory, as the Starmie Doll is buried where you're very unlikely to find it by mistake. Here's how to get to it, but bear in mind that all of this is only applicable if you've got the paid Pokopia Bubbly Basin DLC.
How to get the Starmie Doll in Pokopia
The logical way to get the Pokopia Starmie Doll is to progress the Bubbly Basin story, by raising the environment level to 3 and completing Popplio's next request to find their friends. At this point, you'll meet Frillish in a cave, and it's here that you can find the Starmie Doll.
However, you can head to this location with any Search Pokemon and a Dowsing machine to find the doll early. So, doing this depends on whether you want to play through as intended or head straight to the Pokopia Dream Island.
If you do want to get the Starmie Doll as soon as possible, find its exact location below.
Starmie Doll location
The Pokopia Starmie Doll is located in a cave to the northwest of Bubbly Basin, which is at first blocked by rock. You can see the cave entrance in the image above.
With a Search Pokemon in tow and a Dowsing Machine to hand, you can now head to the location above to hunt down the doll. There are a few different pieces of treasure to find here, so keep going until you reach the special doll. You'll find the Starmie Doll buried in a patch of Star-spotted Rock in the first area with minecart rails, just after a patch of pink Mossy Ocean Soil. You'll need to head back underwater and destroy a couple of netting walls on your way there.
In this area, get your Dowsing Machine out and press 'A', then your Search companion will lead you to the correct area.
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