Lego Batman 3: Beyond Gotham character unlocks guide

Non-token Characters 

Batman: Complete "Pursuers in the Sewers."
Robin: Complete "Pursuers in the Sewers."
Alfred: Complete "Breaking BATS!"
Cyborg: Complete "Space suits you, Sir!"
The Flash: Complete "Space suits you, Sir!"
Superman: Complete "Space Station Infestation."
Wonder Woman: Complete "Space Station Infestation."
Killer Croc: Complete "The Big Grapple."
The Joker: Complete "The Big Grapple."
Lex Luthor: Complete "The Big Grapple."
Cheetah: Complete "The Big Grapple."
Solomon Grundy: Complete "The Big Grapple."
Star Sapphire: Complete "Power of Love."
Saint Walker: Complete "A Blue Hope."
Indigo-1: Complete "Jailhouse Nok."
Brainiac: Complete "Breaking the Ice."
Batman (1966): Complete "Same Bat-time! Same Bat-channel!"
Robin (1966): Complete "Same Bat-time! Same Bat-channel!"
Batgirl (1966): Complete "Same Bat-time! Same Bat-channel!"
The Joker (1966): Complete "Same Bat-time! Same Bat-channel!"

Adam West: Rescue all 30 Adam Wests in peril.
Green Loontern: Complete all of his quests on every Lantern planet.

For these final two, refer to our Gold Brick locations guide.

Story Mode 

Chapter 1: Pursuers in the Sewers 

Croc Henchman (Story Mode)

After draining the water at the start of the level, hop down the ladder to the southern area to find some ducks and a paddle boat. Hop into the boat and mow down the four ducks in the area to spawn the token.

Bane (Free Play)

At the start of the second area is some water you can freeze with Superman's breath. Do so to build an ice sculpture, then melt it with laser vision to grab the token inside.

Black Manta (Free Play)

Now to talk to Bat-Mite, and he'll ask for a special pair of pants. Where could those be?

On the right side of the area is a pipe hole covered in magnetic bars. Use a magnetic character to remove them, then hop inside to find a new area. Use a magnetic move again on the box right near the entrance to find the pants. Return them to Bat-Mite for a character token.

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